Superheater Tube From Boiler

Posted on April 6th, 2016 by Met-Tech

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Analysis of T11 Boiler Superheater Tube Rupture


SUMMARY:

Metallurgical Technologies, Inc. examined a failed superheater tube from XXXXXX X XXX Boiler #7. The ASME SA-213 Grade T11 tube had been in service for 6 to 8 years until failure. The mode of failure was short-term stress rupture due to significant overheating. The microstructure and oxide scale thickness indicated higher than design operating temperatures. The tube had experienced multiple overheating events. At least one of these events had resulted in tube metal temperatures exceeding 1350°F. The internal surfaces had a thick, exfoliated scale that was primarily the result of repeated overheating events. The scale was also a minor contributor to the overheating.

ANALYSIS:

Visual Examination

The failed superheater tube sample is shown as received in Figure 1. The hot side had a 1-inch longitudinal rupture. Wuestite (FeO), which is dark silver-grey form of iron oxide, was visually evident 6 inches on either side of the rupture on the OD surface. The OD scale was partially exfoliated.

A close-up of the rupture site is shown in Figure 2. The rupture was relatively thin-lipped and the tube had visibly bulged at the rupture. Multiple, wide, short, longitudinal cracks were in the vicinity of the rupture (Figure 3). The longitudinal cracks extended to one of the cut ends of the tube (Figure 4). This indicates that all of the damaged tubing may not have been removed from the boiler.

Loose sheets of scale were present inside the tube (Figure 5). The thickness of the loose scale was measured. The majority of the thick pieces measured 0.030 inch. The thickest piece measured 0.035 inch. The internal surface of the tube had a thick, partially exfoliated oxide scale (Figure 6).

Tube Material Chemical Composition

A specimen was cut from the tube and analyzed for its chemical composition using an optical emission spectrometer in accordance with ASTM E415. The results are presented in Table 1 where it may be seen that the composition met the chemical requirements for SA-213, Grade T11 tubing.

Tube Dimensions

A transverse ring section was cut from the tube at the rupture site. The internal and external scale/deposits were removed by glass bead blasting, and the ring dimensions were measured. The results are presented in Table 2. The original tube dimensions were not reported. Assuming that no swelling had occurred 90° away from the rupture, the OD had swelled by roughly 15% at the rupture. The rupture was also thin-lipped. The minimum measured wall thickness on the ring section was 0.023 inch at the rupture. The thickest portion measured 0.162 inch, 90° away.

Metallography

Transverse metallographic cross-sections were taken from the tube through the rupture and at the tube end at a location containing the previously noted longitudinal cracks. The samples were prepared for metallographic examination in accordance with ASTM E3. Etching was performed in accordance with ASTM E407 revealing the microstructure which was examined using an optical microscope in accordance with ASTM E883.

The metallographic cross-section through the middle of the rupture is shown in Figures 7 and 8. The rupture edges were relatively thin. Grain elongation and ductile voids were evident in the microstructure adjacent to the rupture.

The microstructure of the tube was examined at the rupture and at the tube section end containing OD cracks. The observed microstructures were similar. The microstructure along the tube OD was mostly decarburized ferrite to a depth of one half the thickness of the tube wall. The carbon content increased progressing toward the tube ID.

The carbides present near the ID were of two types. One type of carbide was heavily spheroidized and agglomerated along grain boundaries. The other type of carbide was present in fine-structured colonies. This duality of carbide types indicates that the tube had been subjected to temperatures exceeding the lower critical transformation temperatures (roughly 1350°F). This structure was observed around the circumference of the tube at both locations. Representative photomicrographs are shown in Figures 9 and 10.

The OD surface at one tube end had small longitudinal cracks. The metallographic cross- section through this area is shown in Figures 11 and 12. The cracks observed on the external surface were cracks in the oxide scale. The cracks were observed to extend into the tube metal in the cross-section. Intergranular oxidation was observed around the cracks. This further indicated high temperature and oxidation damage.

The thickest observed ID oxide layer was observed 90° from the rupture. Much of the oxide had spalled in service and during cross-sectioning in the laboratory. The metallographic cross-section is shown unetched in Figure 13 and etched in Figure 14. Metallic iron was observed along the grain boundaries of the oxide. Etching dissolved the grain boundary iron. Multiple layers of equiaxed and columnar grains in the oxide indicated multiple events of rapid oxidation. Multiple oxide phases were evident. These observations are indicative of multiple events of high-temperature oxidation.

Scanning Electron Microscopy and Energy Dispersive X-ray Spectroscopy

The internal scale was analyzed for its chemical compositions using energy dispersive X-ray spectroscopy (EDS) in accordance with ASTM E1508. The deposits were black and silvery-black in color and highly ferromagnetic. The inner and outer surfaces were analyzed, and the EDS spectra are shown in Figures 15 and 16.

The inner surface of the scale primarily consisted of iron and oxygen with a minor amount of sodium and chromium and a trace amount of silicon. The outer surface of the scale consisted primarily of iron and oxygen with a minor amount of sodium and silicon and a trace amount of chromium. The presence of sodium without phosphorus could indicate the presence of free caustic in steam carry over, and could potentially lead to caustic stress corrosion cracking of other superheater tubes.

Hardness Test

The hardness of the tubes per ASTM E18 averaged 67 HRB on the hot side and 69 HRB on the cold side. The hardness was consistent with the observed microstructure. The decarburization and carbide spheroidization in service had softened the tube from its initial hardness. The initial hardness was likely greater than 69 HRB.

CONCLUSIONS:

  • The tube had failed due to repeated short-term overheat stress rupture. 
  • The microstructure of the tube and oxide scale thickness indicated that the tube metal temperature had been between 1350°F and 1600°F.
  • The overheating likely occurred multiple times as indicated by the oxide scale morphology and the tube metal microstructure.
  • The tube material was confirmed to be SA-213 Grade T11.
  • The internal scale chemical composition may indicate the presence of free caustic and there is a potential for stress corrosion cracking.

CHEMICAL ANALYSIS

Table 1

Chemical Composition of Tube (in wt. %)

 

C

Mn

P

S

Si

Cr

Mo

Tube

0.14

0.45

0.007

0.006

0.61

1.05

0.46

 

 

 

 

 

 

 

 

SA213-T11

0.05 – 0.15

0.30 – 0.60

0.025 max.

0.025 max.

0.50 – 1.00

1.00 -1.50

0.44 – 0.65

Table 2:

Dimensions of Ring Section from Tube (inch)

Diameter

Outer

Inner

AE

2.158

1.859

BF

2.160

1.909

CG

2.191

2.021

DH

2.181

1.901

 

Wall Thickness

 

Hot

Side

A

0.162

 

Cold

Side

E

0.140

B

0.123

F

0.140

C

0.023

G

0.147

D

0.141

H

0.144

IMAGES:

ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 1: The hot side (top) and cold side (bottom) of the superheater tube is shown as received. The hot side had a longitudinal rupture. The iron oxide, wuestite, was evident 6 inches on either side of the rupture. The OD scale was partially exfoliated.

ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 2: The rupture was relatively thin-lipped and the tube had visibly bulged at the rupture. Note the exfoliated oxide scale.


ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 3: Multiple, wide, longitudinal cracks were in the vicinity of the rupture.

ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 4: The longitudinal cracks extended to one of the cut ends of the tube. This indicates that all of the damaged section may not have been removed from the boiler.


ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 5: Loose, exfoliated scale was present inside the tube.

ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 6: The internal surface of the tube had a thick, partially exfoliated oxide scale.


ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 7: The metallographic cross section through the middle of the rupture is shown. The grains were elongated and the fracture edges were relatively thin. (Nital etch, Mag: 50X)

ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 8: A close-up of the previous figure is shown. Grain elongation and ductile voids were evident in the microstructure adjacent to the rupture. (Nital etch, Mag: 500X)


ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 9: The microstructures near the OD surface were mostly decarburized. The remaining carbides were highly spheroidized and agglomerated along the ferrite grain boundaries. The microstructure 90° from the rupture and at the tube end is shown.(Nital etch, Mag. 500X)


ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 11: The metallographic cross-section through the small longitudinal cracks on the OD surface at the tube end. (Nital etch, Mag. 100X)

ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 12: The area above is shown at higher magnification. Oxidation and cracking are proceeding along the tube’s grain boundaries. (Nital etch, Mag. 500X)


ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 13: The thickest observed ID oxide layer was observed 90° from the rupture. The metallographic cross-section is shown unetched, and metallic iron was observed along the grain boundaries of the oxide (thin white). Multiple oxide phases and multiple layers of equiaxed and columnar grains were evident. (unetched, Mag. 100X)

ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 14: The ID oxide scale along the tube metal interface. The microstructure shows large spheroidized intergranular carbides and clusters of fine spheroidized carbides. (Nital etch, Mag. 500X)


ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 15: The EDS spectrum for the inner layer of the ID scale is shown. The deposit is mainly iron oxide with some chromium oxide and a trace of silicon. Sodium was detected within the scale, but not phosphorous. (Spectrum-A01, 20keV)

ANALYSES OF SUPERHEATER TUBE FROM BOILER

Figure 16: The EDS spectrum of the outer layer of the ID scale is shown. Sodium was still present, but chromium was absent in the outer layer. (Spectrum -A02, 20keV)

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